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== <span style="color: #FFFFFF;">Remembering</span> == * '''Temperature (T)''' β A macroscopic measure of the average kinetic energy of the particles in a system. * '''Heat (Q)''' β Energy transferred between systems due to a temperature difference. * '''Work (W)''' β Energy transferred by mechanical means. * '''Entropy (S)''' β A measure of the disorder or randomness of a system; also defined as the number of microscopic configurations. * '''Internal Energy (U)''' β The total energy contained within a system. * '''Zeroth Law''' β If two systems are in thermal equilibrium with a third, they are in equilibrium with each other (defines temperature). * '''First Law''' β Conservation of energy: ΞU = Q - W. * '''Second Law''' β The total entropy of an isolated system can never decrease over time (defines the arrow of time). * '''Third Law''' β As temperature approaches absolute zero, the entropy of a system approaches a constant minimum. * '''Enthalpy (H)''' β Total heat content of a system: H = U + PV. * '''Gibbs Free Energy (G)''' β Energy available to do work at constant temperature and pressure; determines reaction spontaneity. * '''Boltzmann Constant (k)''' β Relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature. * '''Partition Function (Z)''' β The central object of statistical mechanics; encodes the statistical properties of a system in equilibrium. * '''Microstate''' β A specific microscopic configuration of a system (positions and momenta of all particles). * '''Macrostate''' β Defined by macroscopic parameters (P, V, T). </div> <div style="background-color: #006400; color: #FFFFFF; padding: 20px; border-radius: 8px; margin-bottom: 15px;">
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